{"id":4749,"date":"2024-11-27T10:08:53","date_gmt":"2024-11-27T02:08:53","guid":{"rendered":"\/\/www.rushplease.com\/?p=4749"},"modified":"2024-11-27T10:08:53","modified_gmt":"2024-11-27T02:08:53","slug":"%e9%93%81%e5%82%ac%e5%8c%96%e7%9a%84%e7%ab%af%e7%82%94%e4%b9%99%e7%83%af%e5%9f%ba%e9%94%8c%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.rushplease.com\/archives\/4749","title":{"rendered":"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94"},"content":{"rendered":"<p><a href=\"\/\/www.rushplease.com\/\" target=\"_self\" rel=\"noopener\"><strong>\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c<\/strong><\/a>\u5316\u53cd\u5e94<\/p>\n<p>\u6709\u673a\u950c\u8bd5\u5242\u662f\u73b0\u4ee3\u5408\u6210\u5316\u5b66\u6700\u5e38\u7528\u7684\u91d1\u5c5e\u8bd5\u5242\u4e4b\u4e00\u3002\u7094\u70c3\u7684\u78b3\u950c\u5316\u53cd\u5e94\u662f\u5408\u6210\u6709\u673a\u950c\u8bd5\u5242\u7684\u91cd\u8981\u65b9\u6cd5\uff0c\u4f46\u662f\u76ee\u524d\u666e\u904d\u5b58\u5728\u65e0\u6cd5\u8010\u53d7\u7aef\u7094\u7684\u6c22\u548c\u5f15\u5165\u7684\u78b3\u57fa\u56e2\u96be\u4ee5\u8f6c\u5316\u7b49\u95ee\u9898\uff0c\u4e25\u91cd\u9650\u5236\u4e86\u8be5\u53cd\u5e94\u7684\u5e94\u7528\u3002\u7094\u70c3\u7684\u50ac\u5316\u4e59\u70ef\u57fa\u950c\u5316\uff0c\u53ef\u4ee5\u5728\u7094\u70c3\u4e24\u7aef\u540c\u65f6\u5f15\u5165\u6613\u4e8e\u8f6c\u5316\u7684\u70ef\u57fa\u548c\u950c\uff0c\u5728\u5408\u6210\u4e2d\u6709\u91cd\u8981\u7684\u5e94\u7528\u6f5c\u529b\u3002\u7136\u800c\uff0c\u8981\u5b9e\u73b0\u7aef\u7094\u7684\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u9700\u8981\u514b\u670d\u591a\u79cd\u6311\u6218\uff1a\uff081\uff09\u7aef\u7094\u7684\u9178\u6027\u6c22\u80fd\u591f\u6dec\u706d\u50ac\u5316\u5242\uff0c\u6216\u8005\u548c\u950c\u8bd5\u5242\u53d1\u751f\u7f6e\u6362\u53cd\u5e94\uff1b\uff082\uff09\u7aef\u7094\u5bb9\u6613\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u53d1\u751f\u4e8c\u805a\uff0c\u751f\u6210\u70ef\u7094\u5316\u5408\u7269\uff1b\uff083\uff09\u70ef\u57fa\u950c\u4ea7\u7269\u53ef\u80fd\u8fdb\u4e00\u6b65\u548c\u7094\u70c3\u53d1\u751f\u70ef\u57fa\u950c\u5316\uff0c\u751f\u6210\u7094\u70c3\u9f50\u805a\u4ea7\u7269\uff1b\uff084\uff09\u950c\u8bd5\u5242\u5728\u8fc7\u6e21\u91d1\u5c5e\u7684\u50ac\u5316\u4e0b\u53ef\u80fd\u751f\u6210\u81ea\u7531\u57fa\uff0c\u5bfc\u81f4\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\u96be\u4ee5\u63a7\u5236\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6731\u5b88\u975e\u8bfe\u9898\u7ec4\u53d1\u5c55\u4e86\u4e00\u79cd1,10-\u83f2\u7f57\u5549-\u4e9a\u80fa\u914d\u4f53\u4fee\u9970\u7684\u94c1\u50ac\u5316\u5242\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u6781\u5177\u6311\u6218\u7684\u7aef\u7094\u7684\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\uff0c\u4e3a\u6709\u673a\u950c\u8bd5\u5242\u548c\u591a\u53d6\u4ee3\u5171\u8f6d\u70ef\u70c3\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u7684\u9ad8\u6548\u7684\u65b9\u6cd5\u3002\u8be5\u53cd\u5e94\u5177\u6709\u975e\u5e38\u597d\u7684\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u548c\u5e95\u7269\u666e\u9002\u6027\uff0c\u88ab\u6210\u529f\u7528\u4e8e\u7ef4\u751f\u7d20A\u7b49\u91cd\u8981\u751f\u7269\u6d3b\u6027\u5206\u5b50\u7684\u7b80\u6377\u5408\u6210\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u5408\u6210\u6548\u7387\u3002\u7814\u7a76\u6210\u679c\u8fd1\u671f\u4e3a\u9898\u53d1\u8868\u5728J. Am. Chem. Soc.\uff0c\u5e76\u88ab\u7f16\u8f91\u9009\u4e3aJACS Spotlights\u3002\u535a\u58eb\u751f\u9ec4\u5f3a\u4e3a\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p>\u50ac\u5316\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94<\/p>\n<p>\u7814\u7a76\u53d1\u73b0\uff0c\u90bb\u83f2\u7f57\u5549-\u4e9a\u80fa\u7684\u94c1\u914d\u5408\u7269\u5728\u6a21\u578b\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u7279\u522b\u662f\u90bb\u83f2\u7f57\u5549\u9aa8\u67b69\u4f4d\u5e26\u6709\u5927\u4f4d\u963b2,4,6-\u4e09\u5f02\u4e19\u57fa\u57fa\u7684\u50ac\u5316\u5242C1-C3\u548c2,4,6-\u4e09\u7532\u57fa\u7684\u50ac\u5316\u5242C6\u53ef\u4ee5\u4ee5\u8fd1\u4e4e\u5b9a\u91cf\u7684\u6536\u7387\u548c\u5355\u4e00\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u5f97\u5230\u4e59\u70ef\u57fa\u950c\u5316\u4ea7\u72692\u3002\u5176\u4ed6\u4e09\u9f7f\u914d\u4f53\u3001\u53cc\u9f7f\u6c2e\u914d\u4f53\u3001\u5355\u81a6\u914d\u4f53\u548c\u53cc\u81a6\u914d\u4f53\u5747\u4e0d\u80fd\u7ed9\u51fa\u597d\u7684\u7ed3\u679c\u3002\u5c06C3\u50ac\u5316\u5242\u4e2d\u7684\u4e2d\u5fc3\u91d1\u5c5e\u94c1\u6362\u4e3a\u5176\u5b83\u91d1\u5c5e\uff0c\u53cd\u5e94\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u90fd\u660e\u663e\u964d\u4f4e\u3002<\/p>\n<p>\u53cd\u5e94\u4f18\u5316<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-4750\" src=\"\/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1698331978756-2.jpg\" width=\"300\" height=\"225\" srcset=\"\/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1698331978756-2.jpg 300w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1698331978756-2-220x165.jpg 220w\" sizes=\"(max-width: 300px) 100vw, 300px\" title=\"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u63d2\u56fe\" alt=\"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u63d2\u56fe\" \/><\/p>\n<p>\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u7814\u7a76\u8005\u8003\u5bdf\u4e86\u5e95\u7269\u8303\u56f4\u3002\u8be5\u53cd\u5e94\u6709\u5f88\u597d\u7684\u5b98\u80fd\u56e2\u8010\u53d7\u6027\uff0c\u7532\u6c27\u57fa\u3001\u80fa\u57fa\u3001\u7845\u57fa\u3001\u5def\u57fa\u3001\u916f\u57fa\u3001\u9170\u57fa\u3001\u9170\u80fa\u57fa\u3001\u6c30\u57fa\u3001\u781c\u57fa\u3001\u7f29\u919b\u57fa\u3001\u4e09\u6c1f\u7532\u57fa\u3001\u5364\u7d20\u90fd\u80fd\u8010\u53d7\u3002\u5e26\u6709\u6d3b\u6cfc\u8d28\u5b50\u7684\u5b98\u80fd\u56e2\uff08-NHMe, -OH\uff09\u7684\u7094\u70c3\u5e95\u7269\u540c\u6837\u53ef\u4ee5\u987a\u5229\u53d1\u751f\u53cd\u5e94\u3002\u7a20\u73af\u53d6\u4ee3\u7684\u4e59\u7094\uff082-\u8418\u4e59\u7094\uff09\u548c\u82b3\u6742\u73af\u53d6\u4ee3\u7684\u4e59\u7094\uff08\u544b\u5583\u3001\u567b\u5429\u3001\u5421\u5576\u3001\u5432\u54da\u53d6\u4ee3\u7684\u4e59\u7094\uff09\u540c\u6837\u80fd\u7ed9\u51fa\u8f83\u597d\u7684\u7ed3\u679c\u3002\u9664\u4e86\u4e59\u70ef\u57fa\u950c\uff0c\u5176\u4ed6\u70ef\u57fa\u950c\u4e5f\u53ef\u7528\u4e8e\u8be5\u53cd\u5e94\uff0c\u03b2-\u70f7\u57fa\u3001\u03b1-\u70f7\u57fa\u3001\u53cc\u70f7\u57fa\u3001\u82b3\u57fa\u53d6\u4ee3\u4e59\u70ef\u57fa\u950c\u8bd5\u5242\u53cd\u5e94\u6d3b\u6027\u4f9d\u6b21\u964d\u4f4e\u3002<\/p>\n<p>\u94c1\u50ac\u5316\u82b3\u57fa\u7aef\u7094\u7684\u70ef\u57fa\u950c\u5316\u53cd\u5e94<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-4751\" src=\"\/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199.jpg\" width=\"1280\" height=\"1280\" srcset=\"\/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199.jpg 1280w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-350x350.jpg 350w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-1024x1024.jpg 1024w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-200x200.jpg 200w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-768x768.jpg 768w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-300x300.jpg 300w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-1170x1170.jpg 1170w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1686988440199-220x220.jpg 220w\" sizes=\"(max-width: 1280px) 100vw, 1280px\" title=\"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u63d2\u56fe1\" alt=\"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u63d2\u56fe1\" \/><\/p>\n<p>\u9664\u4e86\u82b3\u57fa\u53d6\u4ee3\u7aef\u7094\uff0c\u5171\u8f6d\u70ef\u7094\uff0c\u8102\u80aa\u57fa\u7aef\u7094\uff0c\u5b98\u80fd\u56e2\u5316\u7094\u70c3\u4e5f\u80fd\u591f\u5728\u94c1\u50ac\u5316\u5242\u4fc3\u8fdb\u4e0b\u987a\u5229\u53d1\u751f\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\uff0c\u4ee5\u8f83\u9ad8\u7684\u6536\u7387\u548c\u5f88\u9ad8\u7684\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u7ed9\u51fa\u76f8\u5e94\u7684\u4ea7\u7269\u3002<\/p>\n<p>\u94c1\u50ac\u5316\u5176\u5b83\u7aef\u7094\u7684\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-4752\" src=\"\/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928.jpg\" width=\"1280\" height=\"720\" srcset=\"\/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928.jpg 1280w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928-350x197.jpg 350w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928-1024x576.jpg 1024w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928-768x432.jpg 768w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928-1170x658.jpg 1170w, \/\/www.rushplease.com\/wp-content\/uploads\/2024\/11\/1638717440928-220x124.jpg 220w\" sizes=\"(max-width: 1280px) 100vw, 1280px\" title=\"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u63d2\u56fe2\" alt=\"\u94c1\u50ac\u5316\u7684\u7aef\u7094\u4e59\u70ef\u57fa\u950c\u5316\u53cd\u5e94\u63d2\u56fe2\" 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= 3\/2\uff09\u65b9\u5f0f\u50ac\u5316\u53cd\u5e94\uff1b\u03b2-\u52a0\u6210\u6d3b\u5316\u80fd\uff0810.9 kcal\/mol\uff09\u6bd4\u03b1-\u52a0\u6210\u6d3b\u5316\u80fd\uff080.9 kcal\/mol\uff09\u9ad8\u4e8610.0 kcal\/mol\uff0c\u4e8c\u6b21\u63d2\u5165\u7684\u6d3b\u5316\u80fd\uff0810.6 kcal\/mol\uff09\u4e5f\u8fdc\u9ad8\u4e8e\u4e00\u6b21\u63d2\u5165\u6d3b\u5316\u80fd\uff080.9 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